This study aims to delve the learning effectiveness of the fifth-grade students with Moodle platform being associated with ADDIE as employed in Chinese course. Results of the research were reached by paired-sample t-test of SPSS analyses based on the grade point obtained in two tests during semester learning and by feedbacks from students according to the questionnaires collected to explore all participants, perception for the online course. Conclusions of this investigation are outlined as follows: Moodle is to be efficacious as utilized in learning Chinese courses and is effectual to obviously narrow the discrete gap of grade point, especially for those lower academic achievement students, with the boy pupils having more advantageous of slimming down degree of dispersion. In addition, Moodle platform seems to be innovative, interesting and helpful to enable students in self-learning on the basis of the collected questionnaires measure in which the learning opinions and attitude of students are the core issues emphasized on. On the contrary, Moodle appears liability in learning deficiency and limitations, while it could be as a reference for pedagogic courses.