RDX Kinetic Model Evaluation by Nth Order Kinetic Algorithms and Model Simulations

ASIA unversity > 醫學暨健康學院 > 食品營養與保健生技學系 > 期刊論文 > Item 310904400/17291

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题名:	RDX Kinetic Model Evaluation by Nth Order Kinetic Algorithms and Model Simulations
作者:	Lung Chang Tsai;Jian Ming Wei;Yung Chuan Chu;Wei Ting Chen;Fang Chang Tsai;Chi Min Shu;Chun Ping Lin
贡献者:	保健營養生技學系
关键词:	1,3,5-Trinitro-1,3,5-Triazmane (RDX);Differential Scanning Calorimetry (DSC);Green Technology;Kinetic Model;Thermokinetic Parameter
日期:	2011-02
上传时间:	2012-11-26 02:31:06 (UTC+0)
摘要:	A kinetic model based on the thermal decomposition of 1,3,5-trinitro-1,3,5-triazmane (RDX) was constructed via differential scanning calorimetry (DSC), well-known kinetic equations, curve-fitting analysis, and simulations of thermal analysis. Our objective was to analyze thermokinetic parameters derived from heating rates used in DSC and compare simulations of thermal decomposition under various kinetic models. Experimental results were strongly dependent on the validity of the kinetic model, which was based on an appropriate mathematical model and a proper method for the evaluation of kinetics. Through six types of kinetic algorithms, a reasonable value of the Ea of the thermal decomposition of RDX was obtained. Finally, this study established a novel green technology for the thermal analysis of reactions and obtained information on the characteristics of thermal decomposition and reaction hazards of RDX.
關聯:	Advanced Materials Research,189-193:1413-1416.
显示于类别:	[食品營養與保健生技學系] 期刊論文

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