Comparison of the Isothermal and Non-isothermal Kinetics for Predicting the Thermal Hazard of Tert-butyl Peroxybenzoate

ASIA unversity > 醫學暨健康學院 > 食品營養與保健生技學系 > 期刊論文 > Item 310904400/17274

請使用永久網址來引用或連結此文件: http://asiair.asia.edu.tw/ir/handle/310904400/17274

題名:	Comparison of the Isothermal and Non-isothermal Kinetics for Predicting the Thermal Hazard of Tert-butyl Peroxybenzoate
作者:	Lin,C.P.;Chang,Y.M.;Tseng, J.M.;You,M.L
貢獻者:	保健營養生技學系
關鍵詞:	Organic Peroxide, Simulation, Tert-Butyl Peroxybenzoate, Thermal Hazard, Thermokinetic
日期:	2011-09
上傳時間:	2012-11-26 02:30:53 (UTC+0)
摘要:	Tert-butyl peroxybenzoate (TBPB), a liquid organic peroxide, has been widely employed in the petrifaction industry as a polymerization formation agent. This study investigated the thermokinetic parameters of TBPB by isothermal kinetic algorithms and non-isothermal kinetic equations, using thermal activity monitor III (TAM III) and differential scanning calorimetry (DSC), respectively. Simulations of 0.5 L, 25 kg, 55 gallon, and 400 kg reactors in liquid thermal explosion models were performed. It is based on the thermal hazard properties, such as the heat of decomposition (∆Hd), activation energy (Ea), self-accelerating decomposition temperature (SADT), control temperature (CT), emergency temperature (ET), and critical temperature (TCR). From the experimental results, the optimal conditions to avoid violent runaway reactions during the storage and transportation of TBPB were determined.
關聯:	Advanced Materials Research, 328-330(PART 1):124-127.
顯示於類別:	[食品營養與保健生技學系] 期刊論文

文件中的檔案:

檔案	描述	大小	格式	瀏覽次數
index.html		0Kb	HTML	255	檢視/開啟

在ASIAIR中所有的資料項目都受到原著作權保護.